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Hi, I’ve got a 6s with no working charging port but before it’s repair I need to backup photos from my photo vault app via WiFi. What’s the best way of doing this to my Windows pc?

Itunes has a connect over Wifi option. What you can do is a full back up of your phone to either iTunes or iCloud. This will backup your photos. Alternatively, you can install the Microsoft onedrive app if you have an account or a Google photos app if you have a google account. You can then automatically upload your photos to your relative account. Please note that online accounts have limited space.